Active control of the electromagnetically induced transparency (EIT) analog is desirable in photonics development. Here, we theoretically and experimentally proposed a novel terahertz (THz) asymmetric metasurface structure that can possess high-sensitivity modulation under extremely low power density by integrating perovskite or graphene. Using the novel metasurface structure with the perovskite coating, the maximum amplitude modulation depth (AMD) of this perovskite-based device reached 490.53% at a low power density of 12.8037mW/cm2. In addition, after the novel THz metasurface structure was combined with graphene, this graphene-based device also achieved high AMD with the maximum AMD being 180.56% at 16.312mW/cm2, and its transmission amplitude could be electrically driven at a low bias voltage. The physical origin of this modulation was explained using a two-oscillator EIT model. This work provides a promising platform for developing high-sensitivity THz sensors, light modulators, and switches.

Biosensors are a focus of research on terahertz metasurfaces. However, reports of ultra-sensitive biosensors based on Dirac points are rare. Here, a new terahertz metasurface is proposed that consists of patterned graphene and perovskites. This serves as an ultra-sensitive Dirac-point-based biosensor for qualitative detection of sericin. Theoretically, sericin may make graphene n-doped and drive the Fermi level to shift from the valence band to the Dirac point, causing a dramatic decrease in conductivity. Correspondingly, the dielectric environment on the metasurface undergoes significant change, which is suited for ultra-sensitive biosensing. In addition, metal halide perovskites, which are up-to-date optoelectronic materials, have a positive effect on the phase during terahertz wave transmission. Thus, this sensor was used to successfully detect sericin with a detection limit of 780 pg/mL, achieved by changing the amplitude and phase. The detection limit of this sensor is as much as one order of magnitude lower than that of sensors in published works. These results show that the Dirac-point-based biosensor is a promising platform for a wide range of ultra-sensitive and qualitative detection in biosensing and biological sciences.

报道了一款基于调制共振泵浦技术的Nd:YVO₄自拉曼激光器。针对全固态自拉曼激光器中热效应严重导致的激光器输出功率及光光效率普遍偏低的问题，合理地将共振泵浦技术和调制泵浦技术相结合，实现了激光器的有效热管控，缓解了激光器的热效应，提高了泵浦上限，从而实现了激光器输出功率和光光效率的大幅提高。当泵浦源的调制频率为10 kHz、占空比为40%、平均泵浦功率为30 W、声光Q开关的调制频率为100 kHz时，获得了最大平均功率为8.57 W的1176 nm斯托克斯光输出，相应光光转换效率28.6%。相较于相同泵浦功率的连续泵浦机制下的实验结果，斯托克斯光平均输出功率提高了42%，光光效率提高了8.5%。实验结果表明：共振泵浦和调制泵浦技术相结合的方式可以有效缓解热效应，提高泵浦功率上限，从而提高自拉曼激光器的输出功率和光光效率。

The preparation of high-quality perovskite films with optimal morphologies is important for achieving high-performance perovskite photodetectors (PPDs). An effective strategy to optimize the morphologies is to add antisolvents during the spin-coating steps. In this work, a novel environment-friendly antisolvent tert-amyl alcohol (TAA) is employed first to improve the quality of perovskite films, which can effectively regulate the formation of an intermediate phase staged in between a liquid precursor phase and a solid perovskite phase due to its moderate polarity and further promote the homogeneous nucleation and crystal growth, thus leading to the formation of high-quality perovskite films and enhanced photodetector performance. As a result, the responsivity of the PPD reaches 1.56 A/W under the illumination of 532 nm laser with the power density of 6.37μW/cm2 at a bias voltage of -2V, which is good responsivity for PPDs with the vertical structure and only CH3NH3PbI3 perovskite as the photosensitive material. The corresponding detectivity reaches 1.47×1012 Jones, while the linear dynamic range reaches 110 dB. These results demonstrate that our developed green antisolvent TAA has remarkable advantages for the fabrication of high-performance PPDs and can provide a reference for similar research work.

Self-powered and flexible ultrabroadband photodetectors (PDs) are desirable in a wide range of applications. The current PDs based on the photothermoelectric (PTE) effect have realized broadband photodetection. However, most of them express low photoresponse and lack of flexibility. In this work, high-performance, self-powered, and flexible PTE PDs based on laser-scribed reduced graphene oxide (LSG)/CsPbBr3 are developed. The comparison experiment with LSG PD and fundamental electric properties show that the LSG/CsPbBr3 device exhibits enhanced ultrabroadband photodetection performance covering ultraviolet to terahertz range with high photoresponsivity of 100 mA/W for 405 nm and 10 mA/W for 118 μm at zero bias voltage, respectively. A response time of 18 ms and flexible experiment are also acquired at room temperature. Moreover, the PTE effect is fully discussed in the LSG/CsPbBr3 device. This work demonstrates that LSG/CsPbBr3 is a promising candidate for the construction of high-performance, flexible, and self-powered ultrabroadband PDs at room temperature.

Highly sensitive broadband photodetection is of critical importance for many applications. However, it is a great challenge to realize broadband photodetection by using a single device. Here we report photodetectors (PDs) based on three-dimensional (3D) graphene foam (GF) photodiodes with asymmetric electrodes, which show an ultra-broadband photoresponse from ultraviolet to microwave for wavelengths ranging from 102 to 106nm. Moreover, the devices exhibit a high photoresponsivity of 103A·W?1, short response time of 43 ms, and 3 dB bandwidth of 80 Hz. The high performance of the devices can be attributed to the photothermoelectric (PTE, also known as the Seebeck) effect in 3D GF photodiodes. The excellent optical, thermal, and electrical properties of 3D GFs offer a superior basis for the fabrication of PTE-based PDs. This work paves the way to realize ultra-broadband and high-sensitivity PDs operated at room temperature.